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The Surprising Behavior of Nb-Doped CsV Sb

Exploring the complex interactions of superconductivity and charge order in a unique material.

J. N. Graham, S. S. Islam, V. Sazgari, Y. Li, H. Deng, G. Janka, Y. Zhong, O. Gerguri, P. Kral, A. Doll, I. Bialo, J. Chang, Z. Salman, A. Suter, T. Prokscha, Y. Yao, K. Okazaki, H. Luetkens, R. Khasanov, Z. Wang, J. -X. Yin, Z. Guguchia

― 5 min read


Nb-Doped CsV Sb Dynamics Nb-Doped CsV Sb Dynamics superconductivity in a unique material. Examining charge order and
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Imagine a material doing a little dance between being normal and being super. This is what happens in certain compounds like Nb-doped CsV Sb. Under the right conditions, this material plays the role of a superconductor, meaning it can conduct electricity without any resistance—pretty cool, right? But there’s a twist. It also has a Charge Order, which is just a fancy way of saying that the electrons in it like to organize themselves in specific patterns.

In this article, we’re going to peel back the layers of this fascinating material. We’ll see how pressure, doping, and other factors can change its behavior. Let’s jump in!

What’s a Superconductor Anyway?

First off, let’s clarify this whole superconductivity thing. Superconductors are materials that can carry electricity without losing energy. This phenomenon typically occurs at very low Temperatures. If you’ve ever watched a magician pull a rabbit out of a hat, that’s a little like what happens when scientists cool these materials down—they reveal their hidden powers!

Now, it’s not just any old superconductor we’re talking about. We’re diving into the world of kagome systems, a unique type of arrangement where atoms form a lattice in a way that looks like interlocking triangles. This structure can lead to some pretty wild interactions between the electrons, creating intriguing phenomena.

Charge Order: The Organized Chaos

In a normal state, the electrons can move freely, but with charge order, they decide to align themselves in patterns. Think of a dance floor where everyone suddenly decides to form a conga line. While it might look fun and organized, it can actually interfere with the material's ability to conduct electricity.

Now, if you mix in some Niobium (Nb), a nifty element, we can change this dance. Doping, or adding small amounts of Nb, adjusts the electron interactions, leading to a transition from this organized charge order to a state where superconductivity can take over.

How Do We Change the Dance?

Great question! You can mess with the dance by applying pressure, changing the temperature, or altering the concentration of niobium. Scientists are like DJs at a party, mixing tracks to see what spins people into a frenzy.

Pressure: Crank It Up!

Applying pressure to our material changes how close the atoms are to one another. Picture a concert where the crowd gets more and more compressed—you can feel the energy change! In the case of Nb-doped CsV Sb, increasing the pressure can enhance its superconducting properties, leading to a higher critical temperature where it can become superconductive.

Temperature: Hot and Cold

The temperature plays a critical role as well. When cooled down, these materials can flip from being normal to superconductive. If someone turns the heat up too high, it might lose that super status. The delicate balance between these two states is like balancing on a see-saw.

Changing Doping Levels: Mixing It Up

By adding more or less niobium, we can also tweak the behaviors of the electrons. It’s as if we’re changing the flavor of our dish by adding spices. Depending on how much Nb we include, we can control whether the material favors superconductivity or charge order.

Observing the Changes

So, how do scientists know what’s happening in these tiny worlds? With a mix of techniques! One of the big tools they use is muon spin rotation, or SR for short.

Imagine tiny particles called muons being shot into our material. They react to the local magnetic environment, telling scientists what’s cooking inside. By observing how these muons behave, researchers can determine whether time-reversal symmetry—the idea that things should look the same if time runs backward—is being broken in the superconducting state.

The Findings: A Game of Depth

After analyzing the material extensively, scientists discovered some surprising things. At certain depths, they found that superconductivity and charge order could actually decouple. In simpler words, the two phenomena were no longer dancing in sync in the bulk of the material, but near the surface, they would synchronize again.

This behavior is like seeing two people in a group dance: they might be in sync at the edge of the dance floor but completely off-beat in the center. The area near the surface displayed a stronger signal of symmetry breaking than what was found deeper down.

The Pressure of Superconductivity

Put pressure on the material and watch it evolve! The study revealed that as pressure increased up to a critical point, the superconducting properties improved significantly. Not only did the critical temperature rise, but the density of superfluid—a measure of how many electrons can flow without resistance—also doubled.

When pressure is applied effectively, it pushes the electrons into a tighter formation, leading them to engage in a more robust superconducting dance.

The Unconventional Nature of Nb-Doped CsV Sb

What sets Nb-doped CsV Sb apart from traditional superconductors is its unusual pairing of electrons. Instead of forming pairs that behave in a straightforward manner, they show behaviors that challenge our conventional understanding of superconductivity, hinting at more complex underlying dynamics.

Conclusion: A New Chapter in Material Science

To wrap things up, the tale of Nb-doped CsV Sb is a story of hidden potentials and intricate dances between electrons. This material showcases how delicate balances and Pressures can unveil surprising behaviors. Scientists continue to explore this fascinating realm, and each discovery helps us understand more about the fundamental principles of superconductivity.

As we unravel these mysteries, who knows what other material secrets we’ll uncover? For now, let’s just appreciate the science and maybe even break into a little jig to celebrate the wonders of superconductivity!

Original Source

Title: Pressure induced transition from chiral charge order to time-reversal symmetry-breaking superconducting state in Nb-doped CsV$_3$Sb$_5$

Abstract: The experimental realisation of unconventional superconductivity and charge order in kagome systems \textit{A}V$_3$Sb$_5$ is of critical importance. We conducted a highly systematic study of Cs(V$_{1-x}$Nb$_x$)$_3$Sb$_5$ with $x$=0.07 (Nb$_{0.07}$-CVS) by employing a unique combination of tuning parameters such as doping, hydrostatic pressure, magnetic fields, and depth, using muon spin rotation, AC susceptibility, and STM. We uncovered tunable magnetism in the normal state of Nb$_{0.07}$-CVS, which transitions to a time-reversal symmetry (TRS) breaking superconducting state under pressure. Specifically, our findings reveal that the bulk of Nb$_{0.07}$-CVS (at depths greater than 20 nm from the surface) experiences TRS breaking below $T^*=40~$K, lower than the charge order onset temperature, $T_\mathrm{CO}$ = 58 K. However, near the surface (within 20 nm from the surface), the TRS breaking signal doubles and onsets at $T_\mathrm{CO}$, indicating that Nb-doping decouples TRS breaking from charge order in the bulk but synchronises them near the surface. Additionally, Nb-doping raises the superconducting critical temperature $T_\mathrm{C}$ from 2.5 K to 4.4 K. Applying hydrostatic pressure enhances both $T_\mathrm{C}$ and the superfluid density by a factor of two, with a critical pressure $p_\mathrm{cr}$ ${\simeq}$ 0.85 GPa, suggesting competition with charge order. Notably, above $p_\mathrm{cr}$, we observe nodeless electron pairing and weak internal fields below $T_\mathrm{C}$, indicating broken TRS in the superconducting state. Overall, these results demonstrate a highly unconventional normal state with a depth-tunable onset of TRS breaking at ambient pressure, a transition to TRS-breaking superconductivity under low hydrostatic pressure, and an unconventional scaling between $T_\mathrm{C}$ and the superfluid density.

Authors: J. N. Graham, S. S. Islam, V. Sazgari, Y. Li, H. Deng, G. Janka, Y. Zhong, O. Gerguri, P. Kral, A. Doll, I. Bialo, J. Chang, Z. Salman, A. Suter, T. Prokscha, Y. Yao, K. Okazaki, H. Luetkens, R. Khasanov, Z. Wang, J. -X. Yin, Z. Guguchia

Last Update: 2024-11-27 00:00:00

Language: English

Source URL: https://arxiv.org/abs/2411.18744

Source PDF: https://arxiv.org/pdf/2411.18744

Licence: https://creativecommons.org/licenses/by/4.0/

Changes: This summary was created with assistance from AI and may have inaccuracies. For accurate information, please refer to the original source documents linked here.

Thank you to arxiv for use of its open access interoperability.

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