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The Role of Carbon Monosulphide in Star Chemistry

Examining the formation and significance of carbon monosulphide in space.

― 6 min read


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In our universe, there are many fascinating processes happening around us. One important area of study is the chemistry of stars and the materials that surround them, known as the interstellar medium. In this space, molecules form and interact, leading to the creation of complex compounds. This article will focus on one specific molecule, carbon monosulphide (CS), and how it forms in different environments.

What is Carbon Monosulphide (CS)?

Carbon monosulphide is a simple molecule made up of one carbon atom and one sulphur atom. It has been observed in various space environments, including diffuse clouds and other areas where stars are being formed. Scientists use CS as a marker to study the density of gas in these regions, which tells us a lot about the materials in our galaxy and beyond.

Understanding how CS forms is essential because it can provide insights into the chemical processes occurring in space. These Reactions can happen in various types of environments, including dark clouds where stars are born and warmer diffuse regions.

The Formation of CS

The formation of CS is not straightforward. It involves several different reactions, some of which involve open-shell species. Open-shell species are molecules that have unpaired electrons, making them highly reactive.

Two significant reactions leading to the formation of CS are as follows:

  1. CH + S → CS + H
  2. C + S → CS + C

These reactions occur in areas with low ionization fractions, meaning there are fewer charged particles that can interfere with the process.

A Closer Look at the Reactions

The Reaction CH + S → CS + H

In the first reaction, we start with a molecule containing carbon and hydrogen (CH) and a sulphur atom (S). When these come together, they can form CS and release a hydrogen atom (H).

This reaction is unique because it presents many possible energy states that can affect how the reaction proceeds. It turns out that at low temperatures (around 10 K), the rate at which this reaction occurs is nearly constant over a range of temperatures. This reaction is significant in cold regions of space where many new stars begin to form.

The Reaction C + S → CS + C

The second reaction involves a carbon atom (C) and a sulphur atom (S). When these react, they produce CS and another carbon atom. This reaction is also important, especially in warmer regions, since it shows a dependency on temperature. At cooler temperatures, the reaction proceeds at a slower rate compared to when it occurs at higher temperatures.

Both reactions were studied using computer models to predict their behavior and how they contribute to the overall abundance of CS in space.

Why Study These Reactions?

Studying these reactions and the rates at which they occur helps scientists understand the Sulfur chemistry within dense Molecular Clouds. These clouds are crucial for star formation, and knowing the chemical processes happening inside them can help us piece together the life cycles of stars.

One major challenge is that many of the sulphur-bearing compounds are not easily observed. While CS is present in small amounts, there are many other sulphur compounds that make up the missing part of the total expected sulphur abundance.

Observing Sulfur in Space

Observations using advanced telescopes have confirmed that much of the sulphur in dense molecular clouds is locked away and not detected easily, leading to an ongoing mystery. Despite the cosmic abundance of sulphur being relatively high, only a few molecules containing sulphur have been observed.

This discrepancy raises questions about where all the sulphur is located. Some scientists propose that it may be hiding in undetected reservoirs in gas and icy grains, or possibly in other forms of matter that remain hidden from our current observational tools.

Current Research Projects

Research initiatives like GEMS (Gas phase Elemental abundances in Molecular clouds) aim to measure the abundances of important elements such as sulfur, carbon, nitrogen, and oxygen in various star-forming regions. By understanding these elements' depletions, scientists can gain insights into the chemical processes that shape our universe.

GEMS investigates the relationships between different elements and how their abundances change with various conditions. This research is complex but vital for a better grasp of space chemistry.

Chemical Models and Predictions

To interpret observations, scientists use chemical models that simulate how different molecules interact and react with one another in various environments. These models require precise reaction rates to be accurate.

The two reactions of interest-CH + S → CS + H and C + S → CS + C-have been evaluated to provide updated reaction rates. The results of these models allow researchers to compare predicted abundances of CS and other molecules to what has been observed in space.

For example, in regions like TMC 1, which is known for various sulfur-bearing compounds, the new reaction rates have been implemented into existing chemical networks to see how well they match actual observations.

Results from Chemical Models

Chemical calculations using the newly updated reaction rates have shown interesting results when compared to observational data from sources like TMC 1. The models demonstrate reasonable agreement with observed carbon monosulphide levels, although not all species can be accurately predicted simultaneously.

Discrepancies in Observed Abundances

While the predictions align well for many molecules, some, like OCS and NS, do not fit within the expected range based on the new reaction rates. This indicates that there are additional complexities in the chemistry of sulphur-bearing species that require more investigation.

Moreover, it has been noted that the influence of time-how long the chemical processes have been occurring-plays a significant role in measuring the abundances of these species. Results vary significantly based on the different chemical times considered.

Conclusion

In summary, the study of carbon monosulphide and its formation reactions is important for understanding the chemistry of the universe. By investigating the key reactions that create CS and analyzing their rates, scientists can better understand the conditions in molecular clouds and how they relate to star formation and the abundance of elements in space.

The ongoing research aims to fill in the gaps regarding sulphur's presence in the interstellar medium, and while many questions remain, each new piece of information brings us closer to unraveling the mysteries of our universe. The complexity of these reactions and the interactions between various molecules highlight the intricate dance of chemistry that occurs in the vastness of space.

Original Source

Title: Gas phase Elemental abundances in Molecular cloudS (GEMS) VIII. Unlocking the CS chemistry: the CH + S$\rightarrow$ CS + H and C$_2$ + S$\rightarrow$ CS + C reactions

Abstract: We revise the rates of reactions CH + S -> CS + H and C_2 + S -> CS + C, important CS formation routes in dark and diffuse warm gas. We performed ab initio calculations to characterize the main features of all the electronic states correlating to the open shell reactants. For CH+S we have calculated the full potential energy surfaces for the lowest doublet states and the reaction rate constant with a quasi-classical method. For C_2+S, the reaction can only take place through the three lower triplet states, which all present deep insertion wells. A detailed study of the long-range interactions for these triplet states allowed to apply a statistic adiabatic method to determine the rate constants. This study of the CH + S reaction shows that its rate is nearly independent on the temperature in a range of 10-500 K with an almost constant value of 5.5 10^{-11} cm^3/s at temperatures above 100~K. This is a factor \sim 2-3 lower than the value obtained with the capture model. The rate of the reaction C_2 + S depends on the temperature taking values close to 2.0 10^{-10} cm^3/s at low temperatures and increasing to 5. 10^{-10} cm^3/s for temperatures higher than 200~K. Our modeling provides a rate higher than the one currently used by factor of \sim 2. These reactions were selected for involving open-shell species with many degenerate electronic states, and the results obtained in the present detailed calculations provide values which differ a factor of \sim 2-3 from the simpler classical capture method. We have updated the sulphur network with these new rates and compare our results in the prototypical case of TMC1 (CP). We find a reasonable agreement between model predictions and observations with a sulphur depletion factor of 20 relative to the sulphur cosmic abundance, but it is not possible to fit all sulphur-bearing molecules better than a factor of 10 at the same chemical time.

Authors: Carlos M. R. Rocha, Octavio Roncero, Niyazi Bulut, Piotr Zuchowski, David Navarro-Almaida, Asuncion Fuente, Valentine Wakelam, Jean-Christophe Loison, Evelyne Roueff, Javier R. Goicoechea, Gisela Esplugues, Leire Beitia-Antero, Paola Caselli, Valerio Lattanzi, Jaime Pineda, Romane Le Gal, Marina Rodriguez-Baras, Pablo Riviere-Marichalar

Last Update: 2023-07-01 00:00:00

Language: English

Source URL: https://arxiv.org/abs/2307.00311

Source PDF: https://arxiv.org/pdf/2307.00311

Licence: https://creativecommons.org/licenses/by/4.0/

Changes: This summary was created with assistance from AI and may have inaccuracies. For accurate information, please refer to the original source documents linked here.

Thank you to arxiv for use of its open access interoperability.

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