Investigating the Unique Properties of Ce Bi Au
Research focuses on the magnetic and electrical properties of Ce Bi Au material.
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Researchers have been investigating the properties of a material called Ce Bi Au. This material belongs to a group known as cerium-based compounds. The study focuses on how this material behaves under different conditions, looking at its magnetic and electrical properties. Ce Bi Au is notable for its unique crystal structure and behavior compared to similar compounds.
Crystal Structure
Ce Bi Au has a cubic structure that is similar to another compound called Ce Bi Pt, known for its Kondo insulating properties. The structure plays a significant role in determining the material's physical characteristics. When researchers grow single crystals of Ce Bi Au, they follow specific methods to ensure high-quality samples for analysis.
Magnetic Properties
One of the key findings in this research is how Ce Bi Au behaves magnetically. At lower temperatures, specifically below a certain point, it shows Antiferromagnetic order. This means the magnetic moments in the material align in opposite directions, creating an overall balance. Researchers measure Magnetic Susceptibility to understand how the material responds to magnetic fields, which shows a specific pattern indicating its magnetic nature.
The magnetic susceptibility indicates that Ce Bi Au exhibits behaviors consistent with local moments, which are often found in materials with complex magnetic interactions. These moments interact in ways that can lead to various magnetic states, making the study of this material particularly interesting.
Heat Capacity
In addition to magnetic properties, the heat capacity of Ce Bi Au is examined. Heat capacity reflects how a material stores and releases heat. The researchers found that at a certain temperature, there is a significant change in the heat capacity, which corresponds to the antiferromagnetic transition. The behavior of heat capacity provides clues about the magnetic interactions within the material.
The researchers also calculate the magnetic entropy, which indicates how much disorder is present in the magnetic arrangement. This is related to the concept of localized moments in Ce Bi Au, suggesting a distinct magnetic ground state.
Electrical Transport Properties
Another critical area of investigation is the electrical transport properties of Ce Bi Au, particularly its Resistivity, which indicates how well the material conducts electricity. The resistivity measurements reveal Semimetallic behavior, meaning that the material conducts electricity but not as efficiently as metals. This semimetallic behavior is a fascinating aspect of Ce Bi Au, especially when compared to other cerium compounds.
The resistivity of Ce Bi Au shows specific trends with temperature changes. As the temperature decreases, the resistivity does not follow a straightforward pattern. Researchers observe a change in how electrical resistance behaves as they alter conditions, including applying hydrostatic pressure. These changes suggest the presence of underlying interactions that affect the mobility of charge carriers within the material.
Effects of Pressure
When pressure is applied to Ce Bi Au, certain properties begin to change. The transition temperature for the antiferromagnetic behavior shifts slightly upward with increased pressure. This means that as the pressure increases, the material's magnetic properties are affected, hinting at the underlying interactions among its components. Researchers noticed that the changes in resistivity under pressure align with theories about how interactions between different types of magnetic forces evolve with pressure.
Theoretical Simulations
In addition to experimental work, researchers use theoretical simulations to help explain the observed behaviors of Ce Bi Au. These simulations involve complex calculations that provide insights into the material's electronic structure and magnetic interactions. They help visualize how electrons behave within the material and predict how it will respond under different conditions.
The simulations confirm that Ce Bi Au has small electron pockets at the Fermi level, aligning with the findings from experimental resistivity measurements. These electron pockets are crucial for understanding the material's semimetallic behavior.
Comparison with Other Compounds
An important aspect of the research involves comparing Ce Bi Au with other members of the cerium-based compound family. For example, compounds like Ce Bi Pt and Ce Bi Pd have different behaviors due to variations in structure and electron arrangements. While Ce Bi Pt exhibits insulating behavior, Ce Bi Au falls into the semimetal category, showcasing the diversity within this group of materials.
The behavior of Ce Bi Au is influenced by the presence of additional elements like gold (Au), which contributes to its unique electronic properties. This highlights the intricate relationship between composition and material behavior.
Implications for Future Research
The findings regarding Ce Bi Au open up new avenues for research. Understanding its properties may lead to advancements in the study of magnetic materials and their applications in technology. Semimetallic materials can have implications for thermoelectric applications, which harness temperature differences to generate electricity.
Moreover, the insights gained from Ce Bi Au may help researchers design new materials with tailored properties for specific applications, such as in electronics or energy systems.
Conclusion
The comprehensive investigation of Ce Bi Au reveals its complex magnetic and electrical properties. The material's unique behaviors under various conditions contribute to our understanding of cerium-based compounds. By studying this material, researchers can gain insights that may apply to a broader range of scientific and technological fields, paving the way for future discoveries and innovations.
Through experimental methods and theoretical simulations, the research on Ce Bi Au not only enhances our knowledge of this specific compound but also enriches the overall field of condensed matter physics and materials science.
Title: Localized f-electron magnetism in the semimetal Ce3Bi4Au3
Abstract: Ce$_{3}$Bi$_{4}$Au$_{3}$ crystallizes in the same non-centrosymmetric cubic structure as the prototypical Kondo insulator Ce$_{3}$Bi$_{4}$Pt$_{3}$. Here we report the physical properties of Ce$_{3}$Bi$_{4}$Au$_{3}$ single crystals using magnetization, thermodynamic, and electrical-transport measurements. Magnetic-susceptibility and heat-capacity data reveal antiferromagnetic (AFM) order below $T_N=3.2$ K. The magnetic entropy $S_{\rm mag}$ reaches $R$ln2 slightly above $T_N$, which suggests localized $4f$-moments in a doublet ground state. Multiple field-induced magnetic transitions are observed at temperatures below $T_N$, which indicate a complex spin structure with competing interactions. Ce$_{3}$Bi$_{4}$Au$_{3}$ shows semimetallic behavior in electrical resistivity measurements in contrast to the majority of reported Cerium-based 343 compounds. Electrical-resistivity measurements under hydrostatic pressure reveal a slight enhancement of $T_N$ under pressures up to 2.3 GPa, which supports a scenario wherein Ce$_{3}$Bi$_{4}$Au$_{3}$ belongs to the far left of the Doniach phase diagram dominated by Ruderman-Kittel-Kasuya-Yosida (RKKY) interactions. Using realistic many-body simulations, we confirm the semi-metallic electronic structure of Ce$_{3}$Bi$_{4}$Au$_{3}$ and quantitatively reproduce its local moment behavior in the paramagnetic state.
Authors: M. O. Ajeesh, S. K. Kushwaha, S. M. Thomas, J. D. Thompson, M. K. Chan, N. Harrison, J. M. Tomczak, P. F. S. Rosa
Last Update: 2023-09-05 00:00:00
Language: English
Source URL: https://arxiv.org/abs/2309.02559
Source PDF: https://arxiv.org/pdf/2309.02559
Licence: https://creativecommons.org/licenses/by/4.0/
Changes: This summary was created with assistance from AI and may have inaccuracies. For accurate information, please refer to the original source documents linked here.
Thank you to arxiv for use of its open access interoperability.