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CsCr Sb: A New Player in Superconductivity

CsCr Sb showcases unique superconducting properties stemming from its kagome lattice structure.

― 5 min read


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This article discusses a new material known as CsCr Sb, which is based on a special arrangement called a Kagome Lattice. In this type of structure, atoms are arranged in a way that leads to unique properties. Specifically, this material shows interesting behavior under certain conditions, including the ability to conduct electricity without resistance, a phenomenon known as Superconductivity.

What is Superconductivity?

Superconductivity is a state where a material can conduct electricity without any energy loss. This happens at very low temperatures. When a material becomes superconductive, it can allow electric current to flow freely. This property has the potential to revolutionize electrical systems, making them much more efficient.

Kagome Lattice Structure

The kagome lattice consists of a repeating pattern that looks like a woven basket. This structure can support various electronic phases, which means it can behave in different ways under different conditions. The arrangement of atoms in CsCr Sb specifically allows for strong interactions between electrons, leading to unusual electrical and magnetic properties.

Discovery of CsCr Sb

Researchers discovered CsCr Sb while investigating materials that might show unusual superconductivity. They found that this material has strong electron correlations and magnetic interactions, which are essential for the formation of superconducting states. Normally, materials with weak electronic interactions do not exhibit superconductivity, but CsCr Sb is different.

Phase Transitions in CsCr Sb

As the temperature drops to around 54 K, CsCr Sb undergoes a series of changes known as phase transitions. These transitions involve shifts in its electronic and magnetic properties. The material displays structural changes, where the arrangement of atoms shifts slightly, likely leading to the formation of ordered states where electrons gather in specific patterns.

Charge Density Waves and Antiferromagnetism

The term charge density wave (CDW) refers to a state where the density of electrons becomes uneven, leading to regions of higher and lower electron density. In CsCr Sb, CDW and another ordered state called antiferromagnetic spin-density wave (SDW) occur together. These states are influenced by the geometric arrangement of the atoms in the kagome lattice.

As pressure is applied to CsCr Sb, the CDW and SDW orders begin to disappear. This suppression allows for the emergence of superconductivity, which appears at a temperature of around 6.4 K. This behavior shows a striking parallel with other known superconductors, particularly those based on iron.

The Effect of Pressure

Applying pressure to CsCr Sb significantly alters its properties. The researchers found that with increasing pressure, the material's resistivity decreases, meaning it becomes more metallic. When the pressure reaches about 4 GPa, the superconducting state appears. This transition illustrates how pressure can shift the balance between different electronic and magnetic states, leading to new and exciting behaviors in the material.

Quantum Critical Points and Non-Fermi-Liquid Behavior

A key concept in this study is the quantum critical point (QCP). This is a specific point in the phase diagram of a material where phase transitions occur. Near this point, CsCr Sb exhibits non-Fermi-liquid behavior, which indicates a breakdown of normal electron behavior. This behavior is often associated with materials that show unconventional superconductivity.

The Electronic Structure of CsCr Sb

To understand the behavior of CsCr Sb better, researchers used theoretical calculations. These calculations reveal how the different energy levels of electrons in the material contribute to its conducting properties. The results show that the electronic states around the Fermi level, where conduction occurs, are influenced significantly by the arrangement of Cr and Sb atoms.

Physical Properties Measurement

Various experiments were conducted to measure the physical properties of CsCr Sb. Using methods like resistivity measurements, researchers were able to determine how the material responds to changes in temperature and pressure. These measurements confirmed the predictions made by theoretical calculations and provided further insights into the nature of the superconducting state.

Structural Analysis

Single crystals of CsCr Sb were grown using a special method to ensure their purity and quality. Various characterization techniques such as X-ray diffraction and electron microscopy were employed to analyze the structure of the crystals. These analyses confirmed the hexagonal arrangement of atoms and provided additional information on how the structural characteristics relate to its physical properties.

Magnetic Properties

The magnetic behavior of CsCr Sb was also examined. It showed that below specific temperatures, the material exhibits magnetic order, indicating strong interactions between local magnetic moments. This antiferromagnetic ordering plays a crucial role in the appearance of superconductivity, as it creates the conditions necessary for electron pairing.

Comparison with Other Kagome Materials

CsCr Sb is part of a broader family of kagome materials, including V Sb. While both materials share a similar structure, their electronic and magnetic behaviors differ significantly. CsCr Sb is characterized by strong electron correlations and complex ordering, which contrast with the more conventional properties of V Sb.

Future Directions of Research

The discovery of CsCr Sb opens up several avenues for future research. Understanding the mechanisms behind its superconductivity can provide insights into other correlated electron systems. Further studies may include investigating how chemical doping can fine-tune its properties or whether similar materials can exhibit superconductivity at higher temperatures.

Conclusion

CsCr Sb represents a unique material with exciting properties that challenge existing theories of superconductivity. Its strong electron correlations and the interplay between various ordered states offer a rich ground for both experimental and theoretical exploration. As research continues, CsCr Sb may contribute significantly to our understanding of unconventional superconductors and the factors that influence their behavior.

Original Source

Title: Superconductivity emerging from density-wave-like order in a correlated kagome metal

Abstract: Unconventional superconductivity (USC) in a highly correlated kagome system has been theoretically proposed for years, yet the experimental realization is hard to achieve. The recently discovered vanadium-based kagome materials, which exhibit both superconductivity and charge density wave (CDW) orders, are nonmagnetic and weakly correlated, thus unlikely host USC as theories proposed. Here we report the discovery of a chromium-based kagome metal, CsCr$_3$Sb$_5$, which is contrastingly characterised by strong electron correlations, frustrated magnetism, and characteristic flat bands close to the Fermi level. Under ambient pressure, it undergoes a concurrent structural and magnetic phase transition at 55 K, accompanying with a stripe-like $4a_0$ structural modulation. At high pressure, the phase transition evolves into two transitions, probably associated with CDW and antiferromagnetic spin-density-wave orderings, respectively. These density-wave (DW)-like orders are gradually suppressed with pressure and, remarkably, a superconducting dome emerges at 3.65-8.0 GPa. The maximum of the superconducting transition temperature, $T_\mathrm{c}^{\mathrm{max}}=$ 6.4 K, appears when the DW-like orders are completely suppressed at 4.2 GPa, and the normal state exhibits a non-Fermi-liquid behaviour, reminiscent of USC and quantum criticality in iron-based superconductors. Our work offers an unprecedented platform for investigating possible USC in a correlated kagome system.

Authors: Yi Liu, Zi-Yi Liu, Jin-Ke Bao, Peng-Tao Yang, Liang-Wen Ji, Si-Qi Wu, Qin-Xin Shen, Jun Luo, Jie Yang, Ji-Yong Liu, Chen-Chao Xu, Wu-Zhang Yang, Wan-Li Chai, Jia-Yi Lu, Chang-Chao Liu, Bo-Sen Wang, Hao Jiang, Qian Tao, Zhi Ren, Xiao-Feng Xu, Chao Cao, Zhu-An Xu, Rui Zhou, Jin-Guang Cheng, Guang-Han Cao

Last Update: 2024-03-16 00:00:00

Language: English

Source URL: https://arxiv.org/abs/2309.13514

Source PDF: https://arxiv.org/pdf/2309.13514

Licence: https://creativecommons.org/licenses/by/4.0/

Changes: This summary was created with assistance from AI and may have inaccuracies. For accurate information, please refer to the original source documents linked here.

Thank you to arxiv for use of its open access interoperability.

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