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New Insights into Graphene Superconductors

Research on twisted trilayer graphene reveals unique superconducting behaviors.

― 5 min read


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Graphene is a single layer of carbon atoms arranged in a two-dimensional honeycomb lattice. It has attracted attention for its unique properties, which can lead to exciting applications in electronics, materials science, and quantum physics. Among its many potential uses, graphene superconductors have emerged as a fascinating area of study. Superconductivity is a property of certain materials that allows them to conduct electricity without resistance when cooled below a specific temperature.

What Are Graphene Superconductors?

Graphene superconductors are materials made from stacked layers of graphene that display superconducting behavior. When two or more layers of graphene are twisted at a specific angle, known as the magic angle, unusual electronic properties arise. These properties make it possible for electrons to pair up, leading to superconductivity. Researchers are particularly interested in these materials because they may behave differently from traditional superconductors, thus opening new avenues for discovery.

The Importance of Superfluid Stiffness

One way to characterize the robustness of a superconductor is through a property called superfluid stiffness. This measure reflects how much energy is needed to change the phase of the superconducting state. In simpler terms, it gives information about the material's ability to maintain its superconducting state and resist changes in current flow. A strong superfluid stiffness means better stability and performance as a superconductor.

Unconventional Superconductors

Most superconductors fall into two categories: conventional and unconventional. Conventional superconductors follow well-known theories and behavior patterns, while unconventional superconductors, like those found in magic-angle twisted graphene, exhibit different characteristics. In unconventional superconductors, the behavior at low temperatures can vary significantly, often resulting from electronic excitations that deviate from traditional models. The unique properties of twisted graphene arise from the correlated electronic states that develop when the layers are arranged at specific angles.

The Discovery of Magic-Angle Twisted Graphene

Magic-angle twisted graphene was discovered when researchers stacked layers of graphene and twisted them at a precise angle of approximately 1.1 degrees. At this angle, the electronic properties of the material changed dramatically. In addition to superconducting states, it also showed signs of complex electronic behavior, suggesting that the material could reveal new ways of pairing electrons and achieving superconductivity.

Nodal-Gap Superconductivity

In this study, scientists measured the superfluid stiffness in a specific type of twisted graphene known as trilayer graphene. Their findings revealed a type of superconductivity called nodal-gap superconductivity. This means that certain directions in the electronic structure of the material allow for the superconducting gap-where electron pairs form-to vanish. The presence of nodes indicates that the pairing does not occur uniformly across the material, leading to novel properties.

The Role of Temperature and Doping

One interesting aspect of superconductivity in twisted graphene is how it changes with temperature and carrier density. Carriers can be thought of as particles that carry electric charge, and their density can influence how the superconductor behaves. By adjusting the temperature and the number of carriers, researchers can observe changes in superfluid stiffness, revealing crucial insights into the underlying mechanisms of superconductivity.

Methodology: Radio-Frequency Techniques

To investigate the properties of Twisted Trilayer Graphene, researchers employed radio-frequency reflectometry techniques. This method involves measuring how the material responds to microwave signals. By analyzing the reflections of these signals, scientists can extract information about the superfluid stiffness and other properties of the superconducting state.

Device Fabrication

To create the twisted trilayer graphene device, researchers used a method called dry transfer. This involved stacking layers of graphene together while ensuring they were twisted at the magic angle. Special care was taken to reduce unwanted capacitance, which could interfere with measurements. The final device was prepared on an insulating substrate, which helps minimize unwanted electrical effects.

Experimental Results

The experiments showed that the twisted trilayer graphene exhibited superconductivity at specific filling factors, meaning there were certain densities of carriers where superconductivity appeared. The researchers observed zero resistance in the material, which is a hallmark of superconductivity. Moreover, the measurements revealed a clear dependence of superfluid stiffness on temperature, reinforcing the idea of nodal-gap superconductivity.

Observations of Nonlinear Effects

In addition to measuring superfluid stiffness, the scientists also investigated nonlinear effects in the material. When a DC supercurrent was introduced, changes in the electronic behavior were observed. This phenomenon suggested that the material exhibited what is known as a nonlinear Meissner effect, which is a characteristic of nodal superconductors. This effect helps confirm the presence of nodes in the superconducting state.

Connecting the Findings to Conventional Theories

The results from the twisted trilayer graphene show similarities to certain behaviors seen in other unconventional superconductors, such as cuprates. Researchers found that the relationship between superfluid stiffness and transition temperature follows patterns observed in other superconducting systems. This suggests that twisted graphene could offer insights into the broader category of unconventional superconductors.

Understanding the Doping Dependence

Doping, or adding impurities to a material, can significantly influence its electronic properties. In the case of twisted trilayer graphene, researchers found that the superfluid stiffness varied with different levels of doping. This relationship provided further evidence for the unique behavior of the material, suggesting that it could be a rich subject for future studies looking to understand the intricacies of superconductivity.

Challenges and Future Directions

Despite the exciting results, there are challenges in studying twisted graphene superconductors. One issue is the inherent disorder that can arise from the twisting process. This disorder can create inhomogeneous superconducting states, making it difficult to achieve consistent measurements. Further research is needed to address these challenges and refine our understanding of the mechanisms behind superconductivity in twisted graphene.

Conclusion

The study of graphene superconductors, particularly magic-angle twisted trilayer graphene, has illuminated new pathways in the field of superconductivity. By measuring superfluid stiffness and observing nonlinear effects, researchers are beginning to unravel the complex behaviors exhibited by these materials. Continued exploration in this area may lead to significant advancements in our understanding of superconductivity and its application in future technologies. The potential for discovering new electronic behaviors in these exotic materials opens exciting possibilities for both fundamental science and practical applications.

Original Source

Title: Superfluid stiffness of twisted multilayer graphene superconductors

Abstract: The robustness of the macroscopic quantum nature of a superconductor can be characterized by the superfluid stiffness, $\rho_s$, a quantity that describes the energy required to vary the phase of the macroscopic quantum wave function. In unconventional superconductors, such as cuprates, the low-temperature behavior of $\rho_s$ drastically differs from that of conventional superconductors due to quasiparticle excitations from gapless points (nodes) in momentum space. Intensive research on the recently discovered magic-angle twisted graphene family has revealed, in addition to superconducting states, strongly correlated electronic states associated with spontaneously broken symmetries, inviting the study of $\rho_s$ to uncover the potentially unconventional nature of its superconductivity. Here we report the measurement of $\rho_s$ in magic-angle twisted trilayer graphene (TTG), revealing unconventional nodal-gap superconductivity. Utilizing radio-frequency reflectometry techniques to measure the kinetic inductive response of superconducting TTG coupled to a microwave resonator, we find a linear temperature dependence of $\rho_s$ at low temperatures and nonlinear Meissner effects in the current bias dependence, both indicating nodal structures in the superconducting order parameter. Furthermore, the doping dependence shows a linear correlation between the zero temperature $\rho_s$ and the superconducting transition temperature $T_c$, reminiscent of Uemura's relation in cuprates, suggesting phase-coherence-limited superconductivity. Our results provide strong evidence for nodal superconductivity in TTG and put strong constraints on the mechanisms of these graphene-based superconductors.

Authors: Abhishek Banerjee, Zeyu Hao, Mary Kreidel, Patrick Ledwith, Isabelle Phinney, Jeong Min Park, Andrew M. Zimmerman, Kenji Watanabe, Takashi Taniguchi, Robert M Westervelt, Pablo Jarillo-Herrero, Pavel A. Volkov, Ashvin Vishwanath, Kin Chung Fong, Philip Kim

Last Update: 2024-06-19 00:00:00

Language: English

Source URL: https://arxiv.org/abs/2406.13742

Source PDF: https://arxiv.org/pdf/2406.13742

Licence: https://creativecommons.org/licenses/by/4.0/

Changes: This summary was created with assistance from AI and may have inaccuracies. For accurate information, please refer to the original source documents linked here.

Thank you to arxiv for use of its open access interoperability.

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