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The Movement and Shape of Active Polymers

Exploring how active polymers behave in fluid environments.

― 5 min read


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Active polymers are special materials that can move on their own. They can be found in nature, like in certain types of bacteria or in parts of our own cells. These polymers have unique behaviors because they interact with the fluids around them. This article discusses how these interactions affect the shape and movement of active polymers, especially when they are pushed along by external forces.

What Are Active Polymers?

Active polymers are long chains of molecules that can change their shape and move due to internal energy sources. They differ from regular, passive polymers that only respond to external forces without generating motion by themselves. Active polymers have specific characteristics that make them fascinating to study. They can behave in ways that are not typically seen in other materials.

The Role of Hydrodynamic Interactions

When active polymers move through a fluid, they don't just drag the fluid along with them. The movement of the fluid can affect the polymer's shape and behavior. This phenomenon is known as hydrodynamic interaction. When active polymers are driven by forces, the surrounding fluid influences how they grow or shrink in size. These interactions play a crucial role in determining how the polymers behave when they are moving.

The Effects of Activity Level

The activity level of a polymer refers to how strong the driving forces acting on it are. Higher Activity Levels lead to more significant interactions with the fluid. This increased activity can cause polymers to change their shape dramatically. For instance, at high activity levels, some semiflexible polymers can take on a helical shape, which is very different from their usual form.

The Shape of Active Polymers

The shape of an active polymer can provide insight into how it interacts with the fluid around it. When studying these polymers, scientists find that hydrodynamic interactions often cause the polymers to shrink in size. This is especially pronounced in polymers that have a certain level of Flexibility, known as semiflexible polymers. When these polymers experience higher activity levels, they often appear nearly three times smaller than their dry, non-moving counterparts.

Simulation Techniques

To study the behavior of active polymers, researchers use computer simulations. One method used is called multiparticle collision dynamics (MPCD). This technique allows scientists to model how fluids behave and how they interact with particles and polymers. Through these simulations, researchers can explore various scenarios and study how changes in fluid conditions affect the conformational properties of active polymers.

Understanding Polymer Dynamics

Active polymers have complex dynamics, which means their movement and interactions can be quite intricate. When these polymers move through a fluid, their shape and the way they orient themselves change. The dynamics include both how the polymer moves through space and how it changes orientation. This behavior is influenced by the interactions between the polymer and the fluid.

Comparing Dry and Wet Polymers

In research, active polymers are often compared in two states: wet (with hydrodynamic interactions) and dry (with no fluid interactions). This comparison helps to reveal how much the fluid affects the polymer's behavior. For instance, studies show that wet polymers have faster movement and greater ability to change orientation than dry polymers. This enhancement is particularly significant in polymers driven by strong external forces.

The Importance of Flexibility

The flexibility of a polymer influences its behavior in significant ways. Flexible polymers behave differently than semiflexible ones. While flexible polymers display consistent Shapes with changes in activity, semiflexible polymers undergo notable transformations in their shapes when subjected to similar conditions. Understanding these differences in flexibility helps researchers predict how active polymers will behave in different environments.

Observations of Polymer Movement

Through simulations, researchers have observed that wet active polymers exhibit faster orientational dynamics. This means they can align themselves more quickly in the direction of their movement. The connection between how the polymer moves and how it interacts with the fluid is crucial for understanding its overall behavior.

The Impact of Environmental Factors

Environmental factors such as fluid viscosity and temperature can also affect how active polymers behave. The viscosity of a fluid describes how thick or thin it is; thicker fluids tend to resist movement more than thinner fluids. In turn, this resistance impacts how active polymers can navigate through their environment.

Summary of Findings

Research shows that fluid-mediated interactions have a critical role in the conformational and dynamical properties of active polymers. These interactions lead to unique behaviors, such as a significant decrease in size and changes in shape as activity levels increase. As the polymer is pushed through a fluid, hydrodynamic interactions can produce fast movements and alterations in direction.

Conclusion

Active polymers are an exciting area of research that continues to reveal new insights into how materials behave in fluid environments. By understanding the interplay between activity levels, flexibility, and fluid dynamics, researchers can better grasp the complex behaviors of these unique materials. The findings have potential applications in numerous fields, including biology, physics, and the development of novel materials that mimic these natural systems.

Original Source

Title: Conformation and dynamics of wet tangentially-driven active filaments

Abstract: We explore the impact of hydrodynamic interactions on the conformational and dynamical properties of wet tangentially-driven active polymers using multiparticle collision dynamics simulations. By analyzing active filaments with varying degrees of flexibility, we find that fluid-mediated interactions significantly influence both their conformation and dynamics. These interactions cause polymer conformations to shrink relative to their dry counterparts, especially for semiflexible polymers at high activity levels, where the average size of wet chains becomes nearly three times smaller, due to local buckling of wet polymers. This hydrodynamic-induced shrinkage is a hallmark of active polymers, as fluid-mediated interactions do not affect conformational properties of passive polymers. Furthermore, for tangentially-driven polymers where activity and conformation are coupled, hydrodynamic interactions significantly enhance the orientational and translational dynamics compared to their dry counterparts.

Authors: Loek van Steijn, Mohammad Fazelzadeh, Sara Jabbari-Farouji

Last Update: 2024-10-22 00:00:00

Language: English

Source URL: https://arxiv.org/abs/2407.17602

Source PDF: https://arxiv.org/pdf/2407.17602

Licence: https://creativecommons.org/licenses/by/4.0/

Changes: This summary was created with assistance from AI and may have inaccuracies. For accurate information, please refer to the original source documents linked here.

Thank you to arxiv for use of its open access interoperability.

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